One of the options that buyers of x-ray fluorescence need to consider relates to the measurement area that they have to work with - the option in question is the collimator package of an XRF analyzer. Collimators focus the x-ray beam onto the measurement area, so the size of that area will affect what collimators should be included in an analyzer. Most XRF analyzers come with a single collimator or package of two, then offer a few optional collimators you may need to add. So, be sure to discuss the smallest possible sample area you may need to measure when discussing your xray fluorescence options.
The typical rule of thumb is that the x-ray beam will spread to about 1.75x what the collimator is. So, a 6mil collimator can be used for an area of about 11mil (Note: we try to work on 2x to be safe). In coating thickness measurements, the area will often be flat and large (ie nuts, bolts) so most standard collimators will work. However, if your sample is smaller than normal, or curved, then you need to review the collimator options closely.
Specifically looking at curved samples, the XRF operator needs to be aware of 'edge effect' that can result in poor readings. Measurements of curved surfaces will be fine when a collimator directs the x-ray onto the center of a curved sample. However, if the collimator is too large then 'edge effect' will result in thicker readings because the sides are averaged into the reported thickness of the coating (see Fig1).
Depending on their size, measurements of cables and wires may actually require a rectangular collimator. The operator would want to line the sample up so that the longer part of the collimator runs along the length of the wire (see Fig 2).
The direction of the wire placement in the chamber is also important to note. Placement will depend on the location of an XRF analyzers detector tube. If the detector is located in front or rear of the collimator then you will want to place the sample in length wise front to back. If the detector is left or right of the collimator place the wire in side to side. The reason for this is because if you were to have a small misalignment with the top of the wire you could fluoresce more, or less, of the signal toward or away from the detector. Proper sample placement will limit this effect. Some systems, like the Hitachi FT110A, have a "locate center" function that uses micro steps of the XY table to scan the thin wire sample for the center point. This can remove the error potentially caused by an operator.
Of course, some measurement areas are so small that only a Micro-XRF analyzer can be considered. The Hitachi FT160 utilizes poly-capillary optics to provide one of the smallest measurement areas on the market (17um FWHM) and can be critical in accurately measuring samples like small solder bumps, BGA's, etc.
Discuss your sample sizes with specialists at Eastern Applied Research in order to confirm what collimators should be included on your next XRF analyzer. We can always run samples to confirm the right collimators are used to meet your testing goals.